High Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water

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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2018-07-16

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Description

This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water–solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level.
Pages
115 pages
Collection
Springer Theses
Parution
2018-07-16
Marque
Springer
EAN papier
9789811316623
EAN PDF
9789811316630

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
5519 Ko
Prix
94,94 €
EAN EPUB
9789811316630

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
3963 Ko
Prix
94,94 €