Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation



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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2014-07-08



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Description
Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
Pages
74 pages
Collection
Springer Theses
Parution
2014-07-08
Marque
Springer
EAN papier
9784431549277
EAN EPUB
9784431549284

Informations sur l'ebook
Nombre pages copiables
0
Nombre pages imprimables
7
Taille du fichier
2068 Ko
Prix
94,94 €