Late Transition Metal-Carboryne Complexes

Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes

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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2012-01-05



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Description
Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.
Pages
134 pages
Collection
Springer Theses
Parution
2012-01-05
Marque
Springer
EAN papier
9783642243608
EAN EPUB
9783642243615

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
13
Taille du fichier
1864 Ko
Prix
94,94 €